Product ID:RP 6410 RESIN
MSDS Date:07/14/1986
FSC:8040
NIIN:00F004822
Kit Part:Y
MSDS Number: BBRBZ

CIBA-GEIGY CORP FORMULATED SYSTEMS GROUP

4917 DAWN AVE
EAST LANSING, MI 48823-5605
US

Emergency Phone: 517-351-5900/800-888-8372

Info Phone: 517-351-5900/800-888-8372

Preparer: M MUNSELL

Cage: 02684

CIBA SPECIALTY CHEMICALS CORPORATION

EAST LANSING, MI 48823-5691 US

Telephone: 517-351-5900

Cage: 02684

DIPHENYLMETHANEDIISOCYANATE (MDI), METHYLENE BIS

CAS: 101-68-8

RTECS: NQ9350000

OSHA PEL 0.02 PPM

ACGIH TLV: 0.051 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYLENE DIPHENYL DIISOCYANATE, POLYPROPYLENE GLYCOL RESIN

CAS: 9048-57-1

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SENSITIZATION, ALLERGIC SKIN &
RESPIRATORY REACTIONS LEADING TO ASTHMA TYPE SPASMS OF BRONCHIAL
TUBES & DIFFICULTY BREATHING. SKIN/EYE IRRITANT. INHALATION: MAY
REDUCE PULMONARY FUNCTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT
Medical Cond Aggravated by Exposure:ASTHMATIC, SKIN/RESPIRATORY
CONDITIONS.

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP &
WATER. INGESTION: IF CONSCIOUS, GIVE WATER. INHALATION: REMOVE TO
FRESH AIR. GIVE OXYGEN/ARTIFICIAL RESPIRATION, IF NEEDED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:325F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER
Fire Fighting Procedures:USE SCBA. DECOMPOSITION/COMBUSTION PRODUCTS
MAY BE TOXIC.
Unusual Fire/Explosion Hazard:AVOID WATER CONTAMINATED IN CLOSED
CONTAINERS/CONFINED SPACES. CARBON DIOXIDE EVOLVED.

Spill Release Procedures:ABSORB W/ABSORBENT MATERIAL/PLACE IN OPEN TOP
CONTAINER. UNDER GOOD VENTILATION, DECONTAMINATE ABSORBENT/SPILL
AREA W/A MIXTURE OF 90% WATER/8% AMMONIA/2% DETERGENT (EXOTHERMIC
REACTION). LEAVE VENTIL ATED 24 HOURS BEFORE DISPOSAL. AVOID
CONTACT.

Handling and Storage Precautions:HARMFUL IF INHALED. KEEP CONTAINER
CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. AVOID BREATHING VAPOR/MIST.
Other Precautions:NUISANCE DUST MAY BE GENERATED WHEN SANDING/SAWING
CURED MATERIAL. HEATED PRODUCT MAY PRODUCE INHALABLE VAPORS.

Respiratory Protection:IN EXCESS OF TLV AN AIR SUPPLIED RESPIRATOR
WOULD BE REQUIRED.
Ventilation:MECHANICAL/EXHAUST IAW/ACGIH RECOMMENDATIONS.
Protective Gloves:IMPERVIOUS
Eye Protection:GOGGLES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health

Vapor Pres:0.027
Vapor Density:>1.0
Spec Gravity:1.11
Solubility in Water:REACTS
Appearance and Odor:CLOUDY LIQUID
Percent Volatiles by Volume:<0.1

Stability Indicator/Materials to Avoid:YES
WATER/ALCOHOLS/STRONG OXIDIZING AGENTS/METAL ORGANIC COMPOUNDS/STRONG
BASES
Stability Condition to Avoid:AVOID PROLONGED HEATING >160F/STORING
<75F.
Hazardous Decomposition Products:CO/CO2/BENZENE/TOLUENE/NITROGEN
OXIDES, HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:CONTAMINATION W/MOISTURE/OTHER
PRODUCTS THAT REACT W/ISOCYANATE.

Waste Disposal Methods:CONSULT QUALIFIED LOCAL/CORPORATE PERSONNEL FOR
METHOD THAT WILL COMPLY WITH LOCAL, STATE AND FEDERAL HEALTH AND
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.